{"id":4385,"date":"2020-11-20T01:21:37","date_gmt":"2020-11-20T01:21:37","guid":{"rendered":"https:\/\/www.aluminiumceramicfiber.com\/?p=4385"},"modified":"2020-11-20T01:21:37","modified_gmt":"2020-11-20T01:21:37","slug":"refining-effect-of-molten-aluminum","status":"publish","type":"post","link":"https:\/\/www.aluminiumceramicfiber.com\/tr\/refining-effect-of-molten-aluminum\/","title":{"rendered":"Erimi\u015f Al\u00fcminyumun Ar\u0131tma Etkisi"},"content":{"rendered":"

Erimi\u015f al\u00fcminyumun ar\u0131tma etkisi, g\u00f6zeneklerin, b\u00fcz\u00fclme bo\u015fluklar\u0131n\u0131n ve kal\u0131nt\u0131lar\u0131n olu\u015fumu \u00fczerinde \u00f6nemli bir etkiye sahiptir ve al\u00fcminyum ala\u015f\u0131ml\u0131 d\u00f6k\u00fcmlerin fiziksel ve mekanik \u00f6zelliklerini do\u011frudan etkiler. Y\u00fcksek kaliteli erimi\u015f al\u00fcminyum olmadan, sonraki i\u015fleme ne kadar geli\u015fmi\u015f olursa olsun, bir kez ortaya \u00e7\u0131kan kusurlar \u00fcr\u00fcnde her zaman mevcut olacakt\u0131r ve y\u00fcksek kaliteli d\u00f6k\u00fcmler elde etmek zordur. Bu nedenle, erimi\u015f al\u00fcminyumdaki gaz ve kal\u0131nt\u0131lara dikkat etmeli ve erimi\u015f al\u00fcminyumdaki gaz ve kal\u0131nt\u0131lar\u0131 gidermek i\u00e7in \u00f6nlemler almal\u0131y\u0131z.<\/p>\n

Erimi\u015f al\u00fcminyumdaki gaz ve kal\u0131nt\u0131lar<\/strong><\/p>\n

Erimi\u015f al\u00fcminyumdaki gaz\u0131n b\u00fcy\u00fck k\u0131sm\u0131 hidrojen (yakla\u015f\u0131k %-90%) olup, bunu azot, oksijen ve karbon monoksit izlemektedir. Hidrojen, kat\u0131 al\u00fcminyumda neredeyse \u00e7\u00f6z\u00fcnmez, ancak s\u0131v\u0131 al\u00fcminyumda y\u00fcksek \u00e7\u00f6z\u00fcn\u00fcrl\u00fc\u011fe sahiptir. Kat\u0131 faz \u00e7izgisinde hidrojenin \u00e7\u00f6z\u00fcn\u00fcrl\u00fc\u011f\u00fc 100 g al\u00fcminyum s\u0131v\u0131s\u0131 ba\u015f\u0131na 0,65 mL ve 0,034 mL'dir (0,1 MPa ko\u015fullar\u0131nda hidrojen); yani kat\u0131-s\u0131v\u0131 fazlar\u0131ndaki hidrojen \u00e7\u00f6z\u00fcn\u00fcrl\u00fc\u011f\u00fc aras\u0131ndaki fark 19,1 kat olup, 100 g erimi\u015f al\u00fcminyum ba\u015f\u0131na normal hidrojen i\u00e7eri\u011fi 0,1-0,4 mL'dir. \u00c7\u00f6z\u00fcn\u00fcrl\u00fck fark\u0131 nedeniyle hidrojen, eriyikten ka\u00e7ma e\u011filimindedir. Hidrojen bas\u0131nc\u0131, y\u00fczey gerilimi ve hidrostatik bas\u0131n\u00e7tan daha y\u00fcksek oldu\u011funda kabarc\u0131klar olu\u015fur ve bu da d\u00f6k\u00fcmde k\u00fc\u00e7\u00fck deliklere neden olur.<\/p>\n

Bu nedenle, al\u00fcminyum ala\u015f\u0131m\u0131 eriyi\u011finin ar\u0131t\u0131lmas\u0131nda temel sorun, al\u00fcminyum ala\u015f\u0131m\u0131n\u0131n hidrojen i\u00e7eri\u011finin y\u00fcksek olmas\u0131 ve mevcut y\u00f6ntemlerin y\u00fcksek kaliteli al\u00fcminyum ala\u015f\u0131ml\u0131 d\u00f6k\u00fcmlerin \u00fcretim gereksinimlerini kar\u015f\u0131layamamas\u0131d\u0131r. Genellikle, 100 g al\u00fcminyum ba\u015f\u0131na hidrojen i\u00e7eri\u011fi 0,1-0,2 mL oldu\u011funda \u00fcretim gereksinimleri temel olarak kar\u015f\u0131lanabilir; \u00f6zel gereksinimler (havac\u0131l\u0131k d\u00f6k\u00fcmleri gibi) i\u00e7in ise 100 g al\u00fcminyum ba\u015f\u0131na hidrojen i\u00e7eri\u011fi 0,06 mL'den az olmal\u0131d\u0131r.<\/p>\n

Katk\u0131 maddeleri, likid\u00fcs seviyesinin \u00fczerindeki s\u0131v\u0131lar d\u0131\u015f\u0131ndaki t\u00fcm kat\u0131 maddeler ve maddelerdir. Erimi\u015f al\u00fcminyumda yayg\u0131n olarak g\u00f6r\u00fclen metalik olmayan safs\u0131zl\u0131klar aras\u0131nda oksitler, nitr\u00fcrler, karb\u00fcrler, bor\u00fcrler vb. bulunur; bunlar \u00e7o\u011funlukla par\u00e7ac\u0131k \u015feklinde olup, tipik par\u00e7ac\u0131k boyutlar\u0131 1-30 \u03bcm aral\u0131\u011f\u0131ndad\u0131r.<\/p>\n

Y\u00fck hari\u00e7 olmak \u00fczere, bu tabaka esas olarak eritme s\u00fcrecindeki kimyasal reaksiyonun bir \u00fcr\u00fcn\u00fcd\u00fcr. Al\u00fcminyum y\u00fczeyindeki oksit tabakas\u0131n\u0131n kal\u0131nl\u0131\u011f\u0131 2-10 \u03bcm\u2019dir ve erime noktas\u0131na yakla\u015ft\u0131\u011f\u0131nda 200 \u03bcm\u2019ye \u00e7\u0131kar. S\u0131v\u0131 y\u00fczeyindeki oksit tabakas\u0131 sadece daha kal\u0131n olmakla kalmaz, ayn\u0131 zamanda yap\u0131s\u0131 da de\u011fi\u015fir; erimi\u015f al\u00fcminyuma bakan taraf yo\u011fundur ve erimi\u015f al\u00fcminyum \u00fczerinde koruyucu bir etkiye sahiptir. Erimi\u015f al\u00fcminyumun d\u0131\u015f\u0131 gev\u015fektir; i\u00e7inde 5-10 \u03bcm \u00e7ap\u0131nda k\u00fc\u00e7\u00fck delikler bulunur ve bu delikler hidrojen, hava ve su buhar\u0131 ile doludur. S\u0131v\u0131 film erimi\u015f al\u00fcminyumun i\u00e7ine kar\u0131\u015ft\u0131r\u0131l\u0131rsa, safs\u0131zl\u0131klar ve gaz miktar\u0131 artar.<\/p>\n

Buna ek olarak, y\u00fcksek ala\u015f\u0131ml\u0131 eriyiklerde al\u00fcminyum-zirkonyum, al\u00fcminyum-titanyum vb. gibi baz\u0131 istenmeyen birincil intermetalik bile\u015fikler ortaya \u00e7\u0131kacakt\u0131r; demir i\u00e7eren al\u00fcminyum ala\u015f\u0131mlar\u0131nda da demir bak\u0131m\u0131ndan zengin al\u00fcminyum-demir fazlar\u0131, al\u00fcminyum-silikon-demir ve al\u00fcminyum-silikon olu\u015facakt\u0131r. Demir faz\u0131, al\u00fcminyum matrisine ciddi zarar veren ve mekanik \u00f6zellikleri etkileyen i\u011fne benzeri bir bile\u015fiktir.<\/p>\n

Al\u00fcminyum ala\u015f\u0131m\u0131ndaki kal\u0131nt\u0131lar ile gaz aras\u0131nda g\u00fc\u00e7l\u00fc bir etkile\u015fim vard\u0131r. Erimi\u015f al\u00fcminyumdaki hidrojen i\u00e7eri\u011fi, kal\u0131nt\u0131lardan b\u00fcy\u00fck \u00f6l\u00e7\u00fcde etkilenir. Kal\u0131nt\u0131 i\u00e7eri\u011fi 0,002% ve 0,02% oldu\u011funda, kar\u015f\u0131l\u0131k gelen hidrojen i\u00e7eri\u011fi 0,2 mL\/100 gAl ve 0,35 mL\/100 gAl'dir. Ayn\u0131 hidrojen i\u00e7eri\u011fi s\u00f6z konusu oldu\u011funda, kal\u0131nt\u0131 i\u00e7eri\u011fi ne kadar y\u00fcksekse, i\u011fne deli\u011fi oran\u0131 da o kadar y\u00fcksek olur; aksine, s\u0131v\u0131 al\u00fcminyum \u00e7ok az safs\u0131zl\u0131k i\u00e7erdi\u011finde, hidrojen i\u00e7eri\u011fi de \u00e7ok d\u00fc\u015f\u00fckt\u00fcr; hidrojen yapay olarak enjekte edilse bile, otomatik olarak \u00e7\u00f6kelir ve h\u0131zla orijinal i\u00e7eri\u011fine geri d\u00f6ner.<\/p>\n

Az miktarda da olsa inkl\u00fczyon bulunsa bile, g\u00f6zenek olu\u015fumu i\u00e7in kritik konsantrasyon de\u011feri \u00f6nemli \u00f6l\u00e7\u00fcde d\u00fc\u015febilir. \u00d6te yandan, inkl\u00fczyon bulunmad\u0131\u011f\u0131nda (veya inkl\u00fczyon i\u00e7eri\u011fi \u00e7ok d\u00fc\u015f\u00fck oldu\u011funda), g\u00f6zenek olu\u015fumu i\u00e7in kritik hidrojen konsantrasyonu 0,3 mL\/100 g Al\u2019ye ula\u015fabilir. Bu nedenle, safs\u0131zl\u0131klar\u0131 ve gaz\u0131 ayn\u0131 anda gidermek e\u015fit derecede \u00f6nemlidir. Hangi ar\u0131tma y\u00f6ntemi kullan\u0131l\u0131rsa kullan\u0131ls\u0131n, gaz giderme ve safs\u0131zl\u0131k giderme i\u015flemleri genellikle birlikte ger\u00e7ekle\u015ftirilir, ancak her birinin kendine \u00f6zg\u00fc bir odak noktas\u0131 vard\u0131r.<\/p>\n

\"Erimi\u015f<\/p>\n

Al\u00fcminyum ala\u015f\u0131m\u0131 eriyik ar\u0131tma teknolojisinin mevcut durumu<\/strong><\/p>\n

G\u00fcn\u00fcm\u00fczde, s\u0131v\u0131 al\u00fcminyumun ar\u0131t\u0131lmas\u0131 ve tanecik inceltilmesinden olu\u015fan kapsaml\u0131 i\u015flem, y\u00fcksek kaliteli al\u00fcminyum ala\u015f\u0131m\u0131 elde etmenin temel sorunudur. Farkl\u0131 \u00fcretim a\u015famalar\u0131na g\u00f6re, erimi\u015f al\u00fcminyumun ar\u0131tma i\u015flemi<\/a> f\u0131r\u0131n i\u00e7i i\u015fleme ve f\u0131r\u0131n d\u0131\u015f\u0131 i\u015fleme olarak ikiye ayr\u0131labilir. Al\u00fcminyum ala\u015f\u0131m\u0131n\u0131n f\u0131r\u0131n i\u00e7i i\u015fleme s\u00fcreci, ar\u0131tma mekanizmas\u0131na g\u00f6re adsorpsiyonlu ar\u0131tma teknolojisi ve adsorpsiyonsuz ar\u0131tma teknolojisi olarak s\u0131n\u0131fland\u0131r\u0131labilir.<\/p>\n

Adsorpsiyon yoluyla ar\u0131tma y\u00f6ntemi, esas olarak ar\u0131tma maddesinin \u00fcretti\u011fi oksitlenmi\u015f kal\u0131nt\u0131lar\u0131 adsorbe etme etkisine dayan\u0131r; bu s\u00fcre\u00e7te, oksitlenmi\u015f kal\u0131nt\u0131lar ve y\u00fczeye ba\u011flanm\u0131\u015f hidrojen giderilerek erimi\u015f al\u00fcminyumun ar\u0131t\u0131lmas\u0131 hedeflenir. Adsorpsiyonsuz ar\u0131tma ise, erimi\u015f al\u00fcminyumun ar\u0131t\u0131lmas\u0131 amac\u0131na ula\u015fmak i\u00e7in di\u011fer fiziksel ve kimyasal etkilere dayan\u0131r.<\/p>\n

Erimi\u015f al\u00fcminyumun adsorpsiyon yoluyla ar\u0131tma etkisi yaln\u0131zca adsorpsiyon aray\u00fcz\u00fcnde ger\u00e7ekle\u015firken, adsorpsiyon d\u0131\u015f\u0131 y\u00f6ntemin ar\u0131tma etkisi ise al\u00fcminyum s\u0131v\u0131s\u0131n\u0131n tamam\u0131na ayn\u0131 anda etki eder. Adsorpsiyon y\u00f6ntemi temel olarak inert gazla temizleme, aktif gazla temizleme, kar\u0131\u015f\u0131k gazla temizleme, klor tuzu (heksakloroetan) ar\u0131tma, toksik olmayan ar\u0131tma maddesi ar\u0131tma, \u00e7\u00f6z\u00fcc\u00fc ar\u0131tma vb. i\u015flemlerini i\u00e7erir; adsorpsiyonsuz y\u00f6ntemler ise ba\u015fl\u0131ca vakum ar\u0131tma y\u00f6ntemi (statik vakum i\u015flemi, dinamik vakum i\u015flemi), ultrasonik ar\u0131tma y\u00f6ntemi, elektromanyetik ar\u0131tma y\u00f6ntemi, bas\u0131n\u00e7l\u0131 kristalizasyon y\u00f6ntemi, nadir toprak elementleri ile hidrojen sabitleme y\u00f6ntemi vb.<\/p>\n

Klorla ar\u0131tma i\u015flemi s\u0131ras\u0131nda adsorpsiyonla ar\u0131tma i\u015flemi<\/a> Bu teknolojide, klor ve s\u0131v\u0131 al\u00fcminyum birle\u015ferek al\u00fcminyum triklor\u00fcr olu\u015fturur; al\u00fcminyum triklor\u00fcr ile hidrojen ise hem fiziksel hem de kimyasal etkileri olan hidrojen klor\u00fcr olu\u015fturur. Ar\u0131tma etkisi a\u00e7\u0131kt\u0131r, ancak \u00e7evreyi kirletir ve insan v\u00fccuduna zararl\u0131d\u0131r. Daha sonra ar\u0131tma i\u00e7in inert gaz (azot ve argon) kullan\u0131lmaya ba\u015fland\u0131; hatta ,999% safl\u0131kta inert gaz bile kullan\u0131ld\u0131, ancak sonu\u00e7lar tatmin edici olmad\u0131 ve maliyet artt\u0131.<\/p>\n

Ar\u0131tma s\u00fcrecini iyile\u015ftirmek i\u00e7in \u00e7e\u015fitli y\u00f6ntemler kullan\u0131lmaktad\u0131r, ancak klorla ar\u0131tman\u0131n sa\u011flad\u0131\u011f\u0131 etki her zaman elde edilememektedir. Son y\u0131llarda, yabanc\u0131 \u00fclkeler kar\u0131\u015f\u0131k gaz ar\u0131tmas\u0131n\u0131, yani inert gaz art\u0131 aktif gaz\u0131 benimsemi\u015ftir; bu, eriyikteki hidrojen giderme etkisini g\u00fc\u00e7lendirebilir, al\u00fcminyum ala\u015f\u0131m\u0131ndaki kal\u0131nt\u0131lar\u0131n giderilmesine yard\u0131mc\u0131 olabilir ve al\u00fcminyum ala\u015f\u0131m\u0131 eriyik y\u00fczeyinde kuru c\u00fcruf olu\u015fturabilir. Ar\u0131tma etkisi. Ayr\u0131ca, klorun kar\u0131\u015ft\u0131rma miktar\u0131 kolayca kontrol edilebilir ve \u00e7evre \u00fczerindeki etkisi b\u00fcy\u00fck de\u011fildir.<\/p>\n

Adsorpsiyonlu ar\u0131tma teknolojisinde, s\u00fcre\u00e7 yenilikleri ve d\u00f6n\u00fc\u015f\u00fcmleri sayesinde bir\u00e7ok pratik al\u00fcminyum s\u0131v\u0131 ar\u0131tma y\u00f6ntemi geli\u015ftirilmi\u015ftir: \u00f6rne\u011fin, inert gazl\u0131 d\u00f6ner gaz giderme, k\u00f6p\u00fck seramik filtrasyon, toz p\u00fcsk\u00fcrtme ar\u0131tmas\u0131 ve d\u00f6ner gaz giderme ile toz p\u00fcsk\u00fcrtme ar\u0131tmas\u0131n\u0131n bir arada kullan\u0131lmas\u0131 gibi.\u00a0 Adsorpsiyonsuz ar\u0131tma teknolojileri aras\u0131nda, nadir toprak elementleri hidrojen sabitleme y\u00f6ntemi de gelecekteki geli\u015fme y\u00f6nlerinden biridir.<\/p>","protected":false},"excerpt":{"rendered":"

The refining effect of molten aluminum has an important influence on the formation of pores, shrinkage cavities and inclusions, and directly affects the physical and mechanical properties of aluminum alloy castings. Without high-quality molten aluminum, even if the subsequent processing is advanced, the defects will always exist in the product once they occur, and high-quality […]<\/p>\n","protected":false},"author":1,"featured_media":4400,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[86],"tags":[],"class_list":["post-4385","post","type-post","status-publish","format-standard","has-post-thumbnail","hentry","category-blog"],"yoast_head":"\nRefining Effect of Molten Aluminum | Adsorption Purification<\/title>\n<meta name=\"description\" content=\"The refining effect of molten aluminum has an important influence on the formation of pores, shrinkage cavities and inclusions.\" \/>\n<meta name=\"robots\" content=\"index, follow, max-snippet:-1, max-image-preview:large, max-video-preview:-1\" \/>\n<link rel=\"canonical\" href=\"https:\/\/www.aluminiumceramicfiber.com\/tr\/refining-effect-of-molten-aluminum\/\" 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